Mines safety bulletin no. 132 | 27 March 2013 | Version 1
Xanthates are a group of chemicals typically used in sulphide flotation in mining applications.
Common xanthate products are sodium ethyl xanthate (SEX), sodium isopropyl xanthate (SIPX), sodium isobutyl xanthate (SIBX) and potassium amyl xanthate (PAX).
Xanthates are classified as liable to spontaneous combustion in the Australian Dangerous Goods (ADG) Code. They pose a number of hazards due to their nature, the vast quantities used in industry and the climate conditions at most Queensland mines using them.
Hazards from xanthates include but are not limited to:
In addition, animal studies indicate xanthates are linked to chronic damage to the liver and neurological system after long-term elevated exposure.
(see the National Industrial Chemicals Notification and Assessment Scheme (NICNAS) Sodium ethyl xanthate assessment report, May 1995, for further information)
Their stability is affected by:
Xanthates are hygroscopic so readily absorb moisture from the air which, at high enough levels, can accelerate decomposition (NICNAS Sodium ethyl xanthate, May 1995).
When xanthates decompose, they produce carbon disulphide (CS2). This is a flammable gas with explosive limits from 1% to 50% by volume in air, and an autoigniton temperature of 90°C. (see the ILO ICSC card list 22 Carbon Disulphide)
The Time Weighted Average exposure is 10ppm (see the Safe Work Australia Hazardous Substances Information System) with an Immediately Dangerous to Life and Health value of 500ppm (see the CDC–NIOSH website). Anecdotal evidence suggests readings of up to 200ppm CS2 were measured when simply opening boxes of xanthate.
Considerable literature exists on the effects of CS2 with studies conducted in various countries. Identified health effects (NICNAS Sodium Ethyl Xanthate, May 1995) include:
Long-term exposure at high levels are responsible for:
In Queensland, xanthates are one of the most used mining reagents, by volume; they have been involved in many chemical incidents in recent years, including:
Safety and health consequences of these incidents included inhalation symptoms (nausea and vomiting), dizziness, burns, the evacuation of surrounding areas, and an explosion that ejected material up to 30m.
Potential consequences could have included serious inhalation symptoms, on-going health concerns and possible fatality.
Incident investigations have highlighted common causes, including some previously identified in readily available literature (e.g the NICNAS report). Some of the common causes include:
Follow the hierarchy of controls so risk is as low as reasonably achievable and at an acceptable level. When elimination or substitution of xanthates with less hazardous reagents isn't feasible due to the metallurgy of the ore, consider the following control recommendations when designing for hazards created by xanthates -
Where feasible substitute liquid for solid xanthate to eliminate mixing steps in the process.
As xanthate fumes and liquids are flammable, AS 1940 The storage and handling of flammable and combustible liquids could assist in identifying possible controls
Ensure storage, handling and mixing procedures include these activities:
Include appropriate respirator or fresh air supply mask, eye protection including goggles, and protective clothing including appropriately rated coveralls, gloves and boots where necessary.
Contact: minesafetyandhealth@dnrm.qld.gov.au
Issued by Queensland Department of Natural Resources and Mines
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All information on this page (Xanthates in mining - https://www.rshq.qld.gov.au/safety-notices/mines/xanthates-in-mining) is correct as of time of printing (Apr 24, 2024 11:25 am).